First I should say that because DevForce EF uses the ADO.NET Entity Framework for the underlying entity model that we're dependent on the rules enforced by EF, which are in general somewhat strict. What you're seeing here is a message from EF as you build your model via the Entity Data Model designer, so the error itself is not raised by DevForce.
Apparently this error is a known limitation in EF - here's what a Microsoft engineer said on the ADO.NET EF forum:
Yes, this is a restriction of the current version of the EF: It does not allow foreign keys which are only partly inside of the primary key. It is not a limitation of the tools, but of the framework itself."
In your situation I don't know if it would make sense to a) not mark the Employee.OrganizationId as part of the primary key, or b) add OrganizationId to the Person table, or c) add surrogate keys to these tables, or d) leave the association unmapped.